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    • 专利摘要:
    method for joining two thermoplastic components and integrated thermoplastic structure two components (32, 34), which may be thermoplastic composite components, are joined by a thermoplastic film (36) forming a thermoplastic joint (31) between the components (32, 34). the thermoplastic film (36) is preferably amorphous and preferably melts during formation of the joint (31).
    公开号:BR112015012036B1
    申请号:R112015012036-9
    申请日:2013-10-16
    公开日:2021-09-08
    发明作者:Sharon Wong；Alexander M. Rubin；Stephen R. Heinz
    申请人:The Boeing Company；
    IPC主号:
    专利说明:

    FIELD OF THE INVENTION 1. Field:
    [001] The present description in general refers to processes for manufacturing composite structures, and deals more particularly with a method for joining composite components using low temperature thermoplastic resin film melting. 2. Fundamentals:
    [002] A variety of techniques are known to join composite laminated components, such as, without limitation, substructures and longitudinal beams used in aerospace applications and more. For example, thermosetting resin laminates can be joined together by cupping, adhesive bonding, or mechanical bonding, while thermoplastic resin laminates can be bonded together by various forms of welding, fusing, adhesive bonding, and mechanical bonding. Joining methods using mechanical fasteners may be undesirable in some applications due to their built-in weight as well as material and installation costs.
    [003] Joining thermoplastic resin laminates without mechanical fasteners is particularly challenging. Adhesive bonding of thermoplastics can require extensive surface preparation of bonding surfaces using advanced and time-consuming processes, such as plasma etching, or labor intensive blasting. Welding techniques require specialized equipment, custom assembly accessories to maintain the component's shape, and have to be performed at relatively high temperatures in the splice line, typically above 700°F (371°C), which can result in reflow of a pre-consolidated component. Remelting a component can result in undesirable changes in the shape and/or material properties of the component.
    [004] A known process for joining two thermoplastic laminated components, referred to as double resin bonding, consists of fusing PEI (polyetherimide) film layers that have been pre-consolidated with bonding surfaces of the components to be joined. Applications of this process, however, are limited because melting PEI films require heating the films to temperatures greater than 475 °F (246 °C). Heating pre-consolidated thermoplastic laminate components at these temperatures can cause unwanted softening, deformation and/or melting of the components.
    [005] Thus, there is a need for a method for joining composite components, including thermoplastics and thermosets, that reduces or eliminates the need for extensive surface preparation, and which can be performed at relatively low temperatures, with shorter cycle times than adhesives of typical thermoset unions. There is also a need for a method of the aforementioned type that allows thermoplastic composite laminates to be joined into components of a different material, such as laminates of thermosetting resin, metals, ceramics and other materials. SUMMARY
    [006] The described embodiments provide a method for joining composite components into integrated structures using low temperature thermoplastic film melting. Pre-consolidated thermoplastic composite (TCP) components can be bonded together with minimal surface preparation, and at relatively low processing temperatures, which are below the melting temperature of the TCP components. Consequently, unwanted softening or remelting of pre-consolidated TCP components is avoided, allowing the original shape and quality of the components to be maintained. The bonding method can reduce cycle times, material and labor costs, while eliminating the need for bonding adhesives, release layers, extensive surface preparation and inspection, specialized processing equipment and/or expensive bonding jigs . The bonding method can be performed in an oven or an autoclave using standard techniques used to process thermoset composites, at temperatures less than 500 °F (260 °C) and at relatively low pressures. Thus, the described method allows a TPC component to be joined into a thermoset composite component at the processing temperatures required to cure the thermoset component. In the aircraft industry, for example, and without limitation, pre-consolidated thermoplastic longitudinal substructures and beams can be joined at lower temperatures with thermoplastic and/or thermoset films without the need for remelting the thermoplastic components, allowing the original shape and quality of the thermoplastic components are maintained. The method can also allow the joining of TPC components into hybrid laminates, metals, ceramics and other materials. The impact resistance of a thermoset composite structure can be improved by joining the thermoset composite components using the described amorphous thermoplastic film to form a thermoplastic fused joint that can absorb energy caused by impacts, shock and/or vibration.
    [007] According to a described embodiment, a method for joining two thermoplastic components is provided. The method comprises producing a first thermoplastic composite component by placing a first amorphous thermoplastic film in a first thermoplastic pre-preg stack, and co-consolidating the first amorphous thermoplastic film and the first thermoplastic pre-preg stack, and producing a second thermoplastic composite component by placing a second amorphous thermoplastic film into a second thermoplastic pre-preg stack, and co-consolidating the second amorphous thermoplastic film and the second thermoplastic pre-preg stack. The method further comprises assembling the first and second thermoplastic composite components, including placing the first and second amorphous thermoplastic films against each other, and pressing the first and second amorphous thermoplastic films together by applying pressure to the first and second thermoplastic composite components o first and second amorphous thermoplastic films are fused together at a temperature below approximately 475 °F (246 °C).
    [008] According to another described embodiment, a thermoplastic composite component is provided for joining a thermoplastic composite component with a thermoset composite component, comprising forming a first composite component co-consolidating an amorphous thermoplastic film with a stack of semi-crystalline thermoplastic pre-preg, and forming the second composite component comprising a thermoset pre-preg stack. The method also includes assembling the first and second components, including placing the amorphous thermoplastic film against the thermoset pre-preg stack, and curing the thermoset pre-preg stack.
    [009] According to another described embodiment, a method is provided for adhering a thermoplastic composite component to a non-thermoplastic component. The method comprises co-consolidating an amorphous thermoplastic film with the semi-crystalline thermoplastic pre-preg stack, and forming an assembly by assembling the co-consolidated amorphous thermoplastic film and a thermoplastic pre-preg stack with a non-thermoplastic component, including placing the amorphous thermoplastic film against the non-thermoplastic component. The method further includes applying pressure to the assembly to force the amorphous thermoplastic film against the non-thermoplastic component, and infusing the amorphous thermoplastic film into the non-thermoplastic component.
    According to a further embodiment, there is provided a method for joining two thermoset composite components, comprising: forming a first thermoset pre-preg stack, and forming a second thermoset pre-preg stack. The method further includes placing a thermoplastic film between the first and second thermoset pre-preg stacks, and consolidating and thermally curing the first and second thermoset prepreg stacks with the thermoplastic film.
    [0011] According to another embodiment, a composite structure is provided comprising first and second cured thermoset composite laminates, and a thermoplastic layer between the cured thermoset composite laminates.
    [0012] According to the further described embodiment, a composite structure comprises a thermoplastic composite laminate, a thermoset composite laminate, and an amorphous thermoplastic film layer joining the thermoplastic composite laminate with the thermoset composite laminate.
    [0013] According to also another embodiment, a method is provided for joining a first thermoplastic composite component into a second thermoplastic composite component. The method comprises co-consolidating a first amorphous thermoplastic film and a first fiber reinforced semi-crystalline thermoplastic polymer matrix composite structure at a first temperature greater than approximately 650°F (343°C) and a first pressure greater than or equal to approximately 100 psi ( 0.69 mPa) to form the first thermoplastic composite component including a first surface rich in amorphous thermoplastic polymer. The method also comprises co-consolidating a second amorphous thermoplastic film and a second fiber reinforced semi-crystalline thermoplastic polymer matrix composite structure at a second temperature greater than approximately 650 F (343 °C) and a second pressure greater than or equal to approximately 100 psi ( 0.69 mPa) to form the second thermoplastic composite component including a second surface rich in amorphous thermoplastic polymer. The method includes mating the first amorphous thermoplastic polymer-rich surface of the first thermoplastic composite component and the second amorphous thermoplastic polymer-rich surface of the second thermoplastic composite component, and heating to a temperature between approximately 450°F and 500°F (232 and 260 °C), and compress, at a pressure between approximately 14.7 and 150 psi (0.1 to 1.03 mPa), the first thermoplastic composite component and the second thermoplastic composite component for a period of time sufficient to bond the amorphous thermoplastic polymer-rich first surface and amorphous thermoplastic polymer-rich second surface without damaging the first thermoplastic composite component and the second thermoplastic composite component.
    [0014] According to yet another embodiment, a method is provided for joining a thermoplastic composite component to an uncured thermoset composite component. The method comprises co-consolidating an amorphous thermoplastic film and a fiber reinforced semi-crystalline thermoplastic polymer matrix composite structure at a temperature greater than approximately 500°F (260°C), and a pressure greater than or equal to approximately 100 psi (0.69 mPa) to form the thermoplastic composite component including a surface rich in amorphous thermoplastic polymer. The method further comprises mating the amorphous thermoplastic polymer-rich surface of the thermoplastic composite component and the uncured thermoset composite component. The method also includes heating, to a temperature of approximately 350 °F (177 °C), and mutually predisposing, to a pressure less than or equal to approximately 100 psi (0.69 mPa), the first thermoplastic composite component and the composite component thermoset uncured for a period of time sufficient to cure the uncured thermoset composite component and bond the first amorphous thermoplastic polymer rich surface thereon without damaging the first thermoplastic composite component.
    [0015] The features, functions and advantages can be achieved independently in various embodiments of the present description, or can be combined in other embodiments as well in which further details can be seen with reference to the following description and drawings. BRIEF DESCRIPTION OF THE DRAWINGS
    [0016] The unpublished resources considered characteristic of the illustrative modalities are presented in the attached claims. The illustrative embodiments, however, as well as a preferred mode of use, its additional aims and advantages, will be better understood by reference to the following detailed description of an illustrative embodiment of the present description when read in conjunction with the accompanying drawings, in which:a Figure 1 is an illustration of a diagrammatic view of an integrated composite structure with thermoplastic composite components joined together by an amorphous thermoplastic film.
    [0017] Figure 2 is a drawing of a photomicrograph showing the cross-sectional interface of the thermoplastic composite components and an amorphous thermoplastic film that form part of the integrated composite structure shown in Figure 1.
    [0018] Figure 3 is a drawing of a photomicrograph showing the fused cross-sectional interface of the thermoplastic composite components of the integrated composite structure.
    [0019] Figures 4 to 7 are diagrammatic cross-sectional illustrations showing the steps of a method for fabricating the integrated composite structure shown in figure 1.
    [0020] Figure 8 is a flowchart illustration of a method for fabricating the integrated composite structure shown in Figure 1.
    [0021] Figure 9 is an illustration of a cross-sectional view of a longitudinal beam in the shape of a pre-consolidated thermoplastic composite hat placed on a pre-consolidated thermoplastic composite film.
    [0022] Figure 10 is an illustration similar to figure 9, but showing the hat-shaped longitudinal beam placed on the film and tooling installed to compress the thermoplastic films together.
    [0023] Figure 11 is an illustration of a cross-sectional view of pre-consolidated thermoplastic composite I-beams assembled with two pre-consolidated thermoplastic composite films.
    [0024] Figure 12 is an illustration similar to Figure 11, but showing the I-beams and films assembled, and tooling installed.
    [0025] Figure 13 is an illustration of a diagrammatic view of a composite structure with thermoplastic and thermoset composite components joined together by an amorphous thermoplastic film.
    [0026] Figure 14 is an illustration of a flowchart of a method for fabricating the composite structure shown in Figure 13.
    [0027] Figure 15 is an illustration of a cross-sectional view of an uncured thermoset composite hat-shaped longitudinal beam placed in a pre-consolidated thermoplastic composite film.
    [0028] Figure 16 is an illustration similar to figure 15, but showing the hat-shaped longitudinal beam placed on the film and tooling installed.
    [0029] Figure 17 is an illustration of a cross-sectional view of a longitudinal beam in a thermoplastic composite hat shape joined in a thermosetting composite film, also showing tooling to maintain the shape of the film during curing.
    [0030] Figure 18 is an illustration of a cross-sectional view of pre-consolidated thermoplastic composite I-beams being joined into two uncured thermoset composite films.
    [0031] Figure 19 is an illustration of a diagrammatic view of a composite structure with a thermoplastic composite component and a non-thermoplastic component joined together by an amorphous thermoplastic film.
    [0032] Figure 20 is an illustration of a flowchart of a method for fabricating the composite structure shown in Figure 19.
    [0033] Figure 21 is an illustration of a diagrammatic view of a composite structure with two thermoset composite components joined together by an amorphous thermoplastic film.
    [0034] Figure 22 is an illustration of a flowchart of a method for fabricating the composite structure shown in Figure 21.
    [0035] FIG. 23 is an illustration of an aircraft production and service methodology flowchart.
    [0036] FIG. 24 is an illustration of a block diagram of an aircraft. DETAILED DESCRIPTION OF THE INVENTION
    [0037] The described embodiments provide a method for joining a thermoplastic composite component (TPC) into another component using a film melting process that can be carried out at relatively low processing temperatures with minimal surface preparation. For example, referring to Figures 1 to 3 according to an embodiment, an integrated TPC structure 30 comprises first and second TPC components 32, 34 respectively, which are joined together by a thermoplastic fused joint 31. The thermoplastic joint 31 is formed by an amorphous thermoplastic film 36 that effectively melts the first and second TPC 32, 34 components together at a processing temperature that is below the melting point of any of the TPC 32, 34 components. As best seen in Figure 3 , each of the first and second TPC components 32, 34 comprises a consolidated thermoplastic composite laminate in which fiber reinforcement layers 48 are held in a thermoplastic resin matrix 39 (Figure 2). Fiber reinforcement 48 can comprise unidirectional or bidirectional fibers, such as, without limitation, glass or carbon fibers, arranged in desired fiber orientations in accordance with a predefined lay-out program (not shown). As will be discussed in more detail below, each of the TPC components 32, 34 may be formed from a stack of a suitable thermoplastic pre-preg which is co-consolidated with a layer of the amorphous thermoplastic film 36.
    [0038] Thermoplastic polymers can be amorphous or semi-crystalline. Amorphous thermoplastic polymers substantially lack positional order on the molecular scale, whereas semicrystalline thermoplastic polymers can contain both crystalline and amorphous regions. The degree of crystallinity of a thermoplastic polymer is affected by structure, temperature, molecular weight, stoichiometry and processing conditions. Semicrystalline thermoplastic polymers have melting temperatures Tm at which the ordered regions of the molecules break and become disordered. In contrast, in amorphous thermoplastic polymers, amorphous regions of the molecules soften over a relatively wide temperature range that is below the melting temperature Tm, referred to as the glass transition temperature Tg. Thermoplastic polymers that are completely amorphous do not fuse and therefore do not have a melting temperature Tm. However, all thermoplastic polymers exhibit a glass transition temperature Tg. In accordance with the described embodiments, resin matrix 39 (Figure 2) may be a semi-crystalline thermoplastic polymer such as, without limitation, members of the polyaryl ether ketone (PAEK) family including, but not limited to, polyether ether ketone ("PEEK" ") and polyether ketone ketone ("PEKK"), and polyphenylsulfone ("PPS"), to name but a few. The resin matrix 39, including the aforementioned semi-crystalline thermoplastic polymers, can have a melt temperature Tm that is above approximately 500°F (260°C), typically above 650°F (343°C).
    [0039] Amorphous thermoplastic film 36 is an amorphous polymer that can have a glass transition temperature Tg above approximately 140 °C and below approximately 500 °F (260 °C), and other mechanical, thermal, and physical properties that are suitable for the application. The particular polymer selected for use as the amorphous thermoplastic film 36 must be compatible with the semicrystalline thermoplastic polymer resin matrix 39, and must be stable at temperatures that are typically used to process thermoplastic parts, for example, and without limitation, of approximately 650 °F (343 °C) to approximately 800 °F (427 °C). In one embodiment, an amorphous thermoplastic film 36 may be employed which exhibits properties that allow it to be co-consolidated with a mating surface of each of the TPC components 32, 34. The amorphous thermoplastic film 36 is co-consolidated with a mating surface of each which of the TPC components 32, 34, at the temperature greater than or equal to that required for consolidation, i.e. the melting temperature Tm of the TPC component, which typically can be in the range between approximately 650 °F (343 °C) and 800 °F (427°C) in order to prepare the TPC component 32, 34 for a secondary splicing process, discussed below. The amorphous thermoplastic film 36 exhibits properties that allow the TPC components 32, 34 to be joined together by melting the two amorphous thermoplastic films 36 together at temperatures below approximately 500°F (260°C), thus avoiding the need for remelting of any of the TPC 32, 34 components during the joining process. By avoiding the need for remelting the TPC components 32, 34 during the joining process, the shape and quality of the TPC components 32, 34 can be maintained.
    [0040] In yet another embodiment, discussed in more detail below, an amorphous thermoplastic film 36 can be used that exhibits properties that allow it to a TPC substrate on a surface of an uncured thermoset pre-preg (not shown) , or on a layer of epoxy film adhesive (not shown) on a thermoset pre-preg of a desired shape. The thermoplastic film 36 bonds the TPC substrate to the uncured thermoset pre-preg or epoxy film adhesive layer, at the curing temperature of the thermoset pre-preg or epoxy film adhesive, which may be, for example, and without limitation, approximately 350 °F (177 °C). The amorphous thermoplastic film 36 may comprise a relatively high temperature tough and rigid engineering material, such as, without limitation, a suitable grade of PES (polyether sulfone), with good thermal stability and creep performance. Amorphous thermoplastic film 36 also has the ability to withstand loads at temperatures up to 180 °F (82 °C) for long periods of time, and the ability to retain mechanical properties up to 210 °C.
    [0041] Referring now simultaneously to Figures 1 to 3, each of the TPC components 32, 34 comprises a consolidated stack of TPC pre-preg formed by reinforcement layers 48 held in a semi-crystalline thermoplastic matrix 39. Each of the TPC components 32, 34 includes a face 33 covered with an amorphous thermoplastic film 36, and pre-consolidated therewith, which forms a mating surface 37 (Figure 2). Amorphous thermoplastic film 36 may comprise one or more layers of amorphous thermoplastic material which are consolidated together to form a desired thickness "t" suitable for the particular application. In one application, for example, and without limitation, the thickness "t" can be between approximately 5 mm and 7 mm.
    [0042] Each of the faces 33 of the TPC component is thus rich in amorphous thermoplastic resin that can fill any crack, opening or void 35 on the face 33. The amorphous thermoplastic films 36 that are pre-consolidated with the faces 33 of the TPC 32 components , 34 may be of the type previously described. When the mating surfaces 37 (Figure 2) of the TPC components 32, 34 are assembled and pressed together face to face, and the amorphous thermoplastic films 36 are fused together as shown in Figure 3, a fused thermoplastic joint 31 is formed. that joins the TPC 32, 34 components.
    [0043] As will be explained below, the amorphous thermoplastic films 36 are respectively consolidated with the corresponding TPC component 32, 34 at the melting temperature Tm of the semicrystalline resin 39 during the pre-consolidation process. Meanwhile, the pre-consolidated TPC components 32, 34 are subsequently joined together by heating the TPC structure 30 to a temperature that is above the glass transition temperature Tg of the amorphous thermoplastic film 36, but is substantially below the melting temperature Tm of the semi-crystalline thermoplastic resin 39. Additional layers (not shown) of the amorphous thermoplastic film 36 may be placed between the mating surfaces 37 when the TPC components 32, 34 are assembled to account for manufacturing and/or assembly tolerances. These additional 36 film layers will fuse with the film layers that have been pre-consolidated with the TCP 32, 34 components.
    [0044] Attention now turns to figures 4 to 7 which graphically illustrate the fabrication of an integrated TPC structure 30 (Figure 1) that requires minimal surface preparation and which can be performed using conventional ovens, vacuum bag processing and/or autoclave. As shown in Figure 4, a semi-crystalline TPC pre-preg stack 32a is assembled, after which an amorphous thermoplastic film 36a is placed on one face 33 of the stack 32a. The assembled TPC pre-preg stack 32a and the film 36a are heated to at least the melting temperature of the TPC pre-preg, further being subjected to a setting pressure, using conventional techniques such as autoclave processing or vacuum bag processing. inside an oven. Heating the TPC pre-preg to its melting temperature also softens the amorphous thermoplastic film 36a, and the applied pressure causes the assembled TPC pre-preg stack 32a and the film 36 to be consolidated together, as shown in the figure. 5. The second component TPC 34 is assembled and pre-consolidated in the same manner as the first component TPC 32 described above.
    [0045] Each of the TPC 32, 34 components having been pre-consolidated in the manner described herein, the TPC 32, 34 components are assembled, as shown in Figure 6, placing the joining surfaces 37 formed by the amorphous thermoplastic films 36a, 36b on components 32, 34 in face-to-face contact with each other. With the two components TPC 32, 34 having been assembled together, they are then heated and subjected to a setting pressure as shown in figure 7. The two components TPC 32, 34 are heated to a temperature which is at least the temperature of glass transition Tg of films 36a, 36b, but which is substantially below the melting temperature Tm of semi-crystalline TPC. For example, the two TPC components 32, 34 can be heated to a temperature that is between approximately 418 °F and approximately 500 °F (260 °C), where the glass transition temperature Tg of film 36a, 36b is about 418 °F. The joining process described with respect to figures 4 to 7 can be carried out using only the tooling required to apply the required set pressure, since the two components TPC 32, 34 are pre-set and only enough pressure is needed to compress and consolidating the two amorphous thermoplastic films 36a, 36b.
    [0046] Figure 8 illustrates the general steps of a method for joining first and second TPC 32, 34 components together. Beginning at step 38, a first TPC component 32 is produced which, as previously described, comprises co-consolidating an amorphous thermoplastic film 36a with a first stack 32a of semi-crystalline TPC pre-preg. In step 40, a second TPC component 34 is produced, which comprises co-consolidating a second amorphous thermoplastic film 36b with a second stack 32b of semi-crystalline TPC pre-preg. In step 42, the first and second TPC components 32, 34 are assembled by bringing the bonding surfaces 37 of the films 36a, 36b together, in face-to-face contact. Although not shown in Figure 8, additional layers of amorphous thermoplastic film 36 may be co-consolidated with either or both of the mating surfaces 37 of steps 38, 40 to account for mounting tolerances. Then, at 44, the amorphous thermoplastic films are compressed together by applying pressure to the first and second TPC components 32, 34. Finally, in step 46, the amorphous thermoplastic films 36a, 36b are fused together by heating the films 36a, 36b at a temperature above its glass transition temperatures Tg, but below a temperature of approximately 500°F (260°C).
    [0047] Attention now turns to figures 9 and 10, which show a typical application of the described method of joining two semi-crystalline TPC components using an amorphous thermoplastic film of the type previously described. In this example, the two semi-crystalline TPC components respectively comprise a hat-shaped TCP longitudinal beam 50, and a TCP film 56. In the illustrated example, the longitudinal beam 50 and film 56 are substantially straight, however, in other examples they may have one or more curves or contours depending on the application. The longitudinal beam 50 includes a pair of laterally extending flanges 52, 54 on which the amorphous thermoplastic film 36a has been pre-consolidated in a manufacturing process similar to that previously described with respect to Figures 4 to 8. Similarly, a pair of films spaced amorphous thermoplastics 36b is pre-consolidated with film 56, in alignment with flanges 52, 54.
    [0048] The longitudinal beam 50 and the film 56 having each been pre-consolidated with their respective films 36a, 36b, the longitudinal beam 50 is then placed 54 on the film 56, in such a way that the amorphous thermoplastic films 36a, 36b remain aligned and come into face-to-face contact with each other.
    [0049] Referring particularly to Figure 10, single upper and lower tools 58, 60 are respectively placed on the flanges 52, 54 and on the bottom of the film 56 in preparation for carrying out a secondary joining process in which the longitudinal beam 50 is joined on film 56 merging films 36a, 36b into each other. It should be noted here that the top and bottom tools 58, 60 need only make contact with the flanges 52, 54 and film 56 in the areas where the amorphous thermoplastic films 36a, 36b are located.
    [0050] Films 36a, 36b are heated to a temperature below approximately 500°F (260°C), but at least to their glass transition temperature Tg, which is below the melting temperature Tm of the fully semi-crystalline TPC longitudinal beam consolidated 50 and film 56. This heating can be accomplished by placing the longitudinal beam 50 and film 56 mounted in an autoclave or oven, although it may be possible to apply localized heat to the area of films 36a, 36b using infrared heating, heated tooling or the like. techniques. The upper and lower tools 58, 60 are forced together by consolidating pressure 62 applied by any suitable device in order to compress the films 36a, 36b together and thereby melt them as they are heated up. of its glass transition temperature Tg. The required set pressure 62 can be applied to tool 58, 60 using a mechanical device such as a press (not shown), or vacuum bag pressure and/or autoclave. A relatively low pressure level, eg less than or equal to approximately 100 psi (0.69 mPa), may be required to bond the two films 36a, 36b together.
    Figures 11 and 12 illustrate another application of the method for joining fully consolidated semi-crystalline TPC I-beams 64 with two semi-crystalline TPC films 56a, 56b. Each of the I-beams 64 includes a pair of spaced apart flanges or covers 68 connected by a central core 66. As best seen in Figure 11, the I-beams 64 and films 56a, 56b are prefabricated and then joined together at a secondary joining operation at relatively low processing temperatures and pressure in accordance with the described method. Each of the I-beams 64 is prefabricated by arranging and forming a TPC pre-preg, after which the amorphous thermoplastic film 36a is placed over each of the caps 68. The films 36a are then co-consolidated with the beams 64 as previously described where TPC I-beam arrangements are heated to their melting temperature, typically around 650 °F (343 °C) or more, and consolidating pressure is applied through suitable tooling (not shown) in order to consolidate the TPC arrangements together with the amorphous thermoplastic films 36a. Semi-crystalline TPC films 56a, 56b are manufactured in a similar manner. The films 56a, 56b are laid out using TPC pre-preg stacks, and the amorphous thermoplastic film 36b is applied to the film 56a, 56b at locations where the beams and 64 are to be joined on the films 56a, 56b. Films 56a, 56b and films 36b are then co-consolidated by heating the TPC pre-preg arrays and the films 36b to the melting temperature of the TPC pre-preg being subjected to consolidation pressure using any suitable device. It should be noted here that, although the I-beams 64 are shown joined to a pair of films 56a, 56b, in other examples, the I-beams 64 can only be joined into a single film 56. Also, covers, flanges or the like composite beam surfaces with other cross-sectional shapes can be joined to one or more composite films using the method described and the amorphous thermoplastic film 36.
    Referring particularly to Figure 12, similar to the application shown in Figures 9 and 10, the I-beams 64 can be joined in films 56a, 56b, using relatively simple upper and lower tools 70, 72 to apply consolidation pressure 76 on I-beams 64 and mounted films 56a, 56b. Consolidation pressure 76 can be applied to tools 70, 72 using a mechanical device such as a press (not shown), vacuum bag processing and/or autoclave. The necessary heating can be achieved using the localized application of heat, or inside an oven or an autoclave. Since the I-beams 64 and films 56a, 56b are pre-consolidated, only sufficient applied pressure is required to effect consolidation of the semi-crystalline thermoplastic films 36a, 36b, for example, less than or equal to approximately 100 psi (0.69 mPa). Similarly, since the I-beams 64 and films 56a, 56b have been pre-consolidated, it is not necessary to reheat the consolidated semi-crystalline TPC to its melting temperature, but rather simply heat the films 36a, 36b to its temperature. glass transition that is below approximately 475 °F (246 °C). Additionally, since both the I-beams 64 and the films 56a, 56b are pre-consolidated, expensive and/or complicated tooling is not required to form or consolidate both the I-beams 64 and the films 56a, 56b. Optionally, it may be desirable to provide lateral tools 74 on each side of the webs 66 in order to avoid undesirable deformation of the webs 66 and/or more effectively transfer the applied loads through the I-beams 64 to the interface of the films 36a, 36b.
    [0053] Referring now to Figure 13, the bonding method described employing an amorphous thermoplastic film 84 can be used to fabricate a composite structure 78 by bonding a semi-crystalline TPC component 80 into a thermosetting composite component 82 at the composite component curing temperature thermoset 82. Typically, the temperature at which the thermoset composite component 82 cures is below the glass transition temperature Tg of the semi-crystalline TPC component 80, typically less than approximately 400°F. The amorphous thermoplastic film 84 remains glassy at the curing temperature of the semi-crystalline TPC component 80. The resin that forms the matrix of the semi-crystalline TPC component 80 achieves a minimal viscosity during cure, and has excellent affinity with the amorphous thermoplastic film 84. Because of this affinity, the thermosetting resin wets the surface of the amorphous thermoplastic film 84. Upon curing, a strong bond is obtained between the amorphous thermoplastic film 84 and the thermosetting resin of the semi-crystalline TPC component 80, producing a molten thermoplastic joint 31 between the semi-crystalline TPC component 82 and the thermosetting component 82. In some embodiments, some distribution of the thermosetting resin may occur in the amorphous thermoplastic film 84, which may reinforce the bond.
    [0054] Figure 14 illustrates the general steps of a method for joining the TPC component 80 with the thermoset component 82. Starting at step 86, a first composite component 80 is formed by co-consolidating an amorphous thermoplastic film 36 and a stack of pre-preg TPC. At step 88, a second composite component 82 is formed, for example, by arranging a thermoset composite pre-preg stack. The thermosetting composite pre-preg may comprise, for example, and without limitation, a thermosetting resin such as epoxy which is reinforced with unidirectional or bidirectional fibers such as carbon fibers, however, other thermosetting resins and fiber materials are possible. Typically, the thermosetting resin may have a cure temperature below approximately 400°F, eg approximately 350°F (177°C).
    [0055] In step 90, the first and second composite components 80, 82 are assembled by placing the amorphous thermoplastic film 36 of the TPC component 80 against the thermoset composite pre-preg stack. Although not shown in Figure 14, an additional layer of amorphous thermoplastic film 36 can optionally be placed on the stack of thermosetting composite prepreg. This additional layer of film 36 later fuses together with film 36 that was previously co-consolidated with the TPC pre-preg stack. The additional layer of film 36 can be used to compensate for manufacturing and/or assembly tolerances and/or problem mismatches that occur during consolidation, thereby ensuring that the thermoplastic fused joint 31 is continuous and has a pre-selected thickness. In step 92, the thermoset composite prepreg stack is cured by heating the thermoset prepreg along with the TPC component 82 to the curing temperature of the thermoset resin. At this curing temperature, the affinity of the thermoset resin for the glassy amorphous thermoplastic film 36 results in the formation of a fused thermoplastic joint 31 between the TPC component 80 and the cured thermoset composite component 82. Thus, it can be seen that during curing of the thermoset composite pre-preg in step 92, the pre-consolidated TPC component 80 does not melt again since the cure temperature of the thermoset resin is less than the melting temperature Tm of the TPC component 80.
    [0056] Figures 15 and 16 illustrate an application of the method for joining a pre-consolidated TPC component into a thermoset composite component using a thermoplastic fused gasket 31 that is formed during the curing of the thermoset composite component, as previously described with respect to the Figures 13 and 14. In this example, a hat-shaped longitudinal beam 94 formed from a thermoset composite such as, without limitation, carbon fiber epoxy, is joined into a pre-consolidated TPC film 98 comprising a pre-consolidated stack 48 of pre-preg TPC. The hat-shaped longitudinal beam 94 includes laterally extending flanges 96. An amorphous thermoplastic film 36 is co-consolidated on the surface of the film 98 at locations corresponding to the placement of the flanges 96 on the film 98. The amorphous thermoplastic film 36 may be of the pre-existing type described and is chosen to match the curing temperature of the thermoset composite used to fabricate the longitudinal beam 94. The thermoset composite hat-shaped longitudinal beam 94 may comprise a multilayer stack of fiber reinforced thermoset resin which is disposed and formed into shape. hat-shaped longitudinal beam 94. The uncured hat-shaped longitudinal beam 94 is then placed 100 in the pre-consolidated TPC film 98, with the flanges 96 in face-to-face contact with the film 36.
    [0057] Referring now particularly to Figure 16, a tool 102 with a cavity mating with the outer mold line of the longitudinal beam 94 is placed on the longitudinal beam 94, and a removable mandrel 104 can be placed within the longitudinal beam 94 in order to react to the consolidating force 106 applied to the hat-shaped longitudinal beam 94 during the curing process. Tool 102 together with mandrel 104 assists in maintaining the shape of the hat-shaped longitudinal beam 94 during curing. The hat-shaped longitudinal beam assembly 94 and film 98 are subjected to a combination of heat and pressure using conventional autoclave or off-autoclave processing techniques. During curing, thermosetting longitudinal beam 94 is heated to the curing temperature of the thermosetting resin, which can be approximately 350 °F (177 °C). During curing, the curing temperature is sufficient to cause the amorphous thermoplastic film 36 to become glassy and fuse with the viscous thermosetting resin, thereby forming a molten thermoplastic joint 31 between the longitudinal beam 94 and the film 98. During curing In the curing process, TPC 98 film retains its shape and does not delaminate or lose desirable quality as it does not remelt at the relatively low temperatures required for curing thermoset longitudinal beam 94.
    [0058] Figure 17 illustrates yet another application of the described joining method using an amorphous thermoplastic film 36 to form a fused thermoplastic joint 31 between two composite components. In this example, a pre-consolidated TPC laminate hat-shaped longitudinal beam 108 is joined by the film 36 to a thermosetting composite laminate film 112. Single top tools 114 are used to apply pressure 118 to the flanges 110 of the longitudinal beam 108 in order to of forcing the pre-consolidated film 36 on the flanges 110 against the thermoset composite film 112 during curing. A lower tool 116 can be employed to maintain the shape of the thermoset composite film 112 during the curing process. Also, an inner mandrel-type tool 104 may be placed within the longitudinal beam 108, bearing on the thermosetting composite film 112, in order to impart binding pressure to the film 112 below the hat portion 108a of the longitudinal beam 108 during consolidation and curing. . During curing, thermoset composite film 112 is heated to its curing temperature, typically approximately 350 F (177°C), which is sufficient to make film 36 glassy and fuse with the viscous thermoset resin of film 112, thereby forming a robust and strong cast thermoplastic gasket 31.
    [0059] Figure 18 illustrates another application of the described method in which the TCP I beams 120 are joined in thermosetting composite film 112a, 112b using the previously described amorphous thermoplastic film 36. This application is similar to that previously described with respect to figures 11 and 12. However, in this example, additional tools can be used to maintain the shape of the films 112a, 112b during the curing process in which the thermosetting resin of the films 112a, 112b becomes sticky and fuses with the glassy amorphous thermoplastic film 36. additional tooling comprises top and bottom tools 126, 128, a center tool 130 and outer tools 132 which collectively engage and contain the surfaces of films 112a, 112b. Side tools 134 may also be positioned on opposite sides of the webs 122 in order to prevent unwanted deformation of the webs 122, and assist in the distribution of the setting force applied to the amorphous thermoplastic film 36 during curing.
    [0060] Although the previously described applications have involved joining a TCP component into a thermoset composite component, it may be possible to employ the described method to join a TPC component into a component formed from other materials such as, without limitation, metals and ceramics . Thus, referring to Figure 19, the previously described amorphous thermoplastic film 36 can be employed to fabricate a composite structure 136 which includes forming a fused thermoplastic joint 31 between a TCP component 138 and a component 140 formed of a non-thermoplastic material such as such as, without limitation, a metal or a ceramic.
    [0061] Beginning at step 142, the amorphous thermoplastic film 36 is co-consolidated with a stack of semi-crystalline TPC pre-preg. At 144, the consolidated TPC co-preg and film 36 are assembled with a non-thermoplastic component 140, placing the co-consolidated amorphous thermoplastic film 36 against the non-thermoplastic component 140. In step 146, pressure is applied to the TPC stack assembly. /film and the non-thermoplastic component 140 co-consolidate in order to press the film 36 against the non-thermoplastic component 140. In step 148, amorphous plastic film 36 is heated to a temperature below approximately 500°F (260°C) but by less than its glass transition temperature, causing it to drain. The fluid film 36 forms a fused thermoplastic joint 31 between the pre-consolidated TCP component 138 and the non-thermoplastic component 140.
    [0062] Figure 21 illustrates yet another application of the method described, in which an amorphous thermoplastic film 36 is employed to manufacture a thermoset composite structure 150 that can have thickness, consistency and/or toughness in the thickness of the bond line improved. The amorphous thermoplastic film 36 is used to produce a fused thermoplastic joint 31 between two thermoset composite components 152. The thermoset composite structure 150 can be produced by the method shown in Figure 22. In steps 156 and 158, the first and second stacks of pre- thermoset preg are respectively formed. In step 160, the amorphous thermoplastic film 36 is placed between the mating surfaces of the first and second uncured thermoset prepreg stacks. In step 162, the first and second thermoset pre-preg stacks are consolidated and thermally cured, along with the amorphous thermoplastic film. During the curing process, the pre-preg and film are heated to the curing temperature of the thermoset resin, typically approximately 350°F (177°C), at which point the amorphous thermoplastic film 36 becomes glassy and fuses with the thermoset resin. slimy. Consolidation pressure applied by vacuum bag processing or autoclave forces the two stacks of thermoset pre-preg against the film 36 to assist in the melting of the thermoset resin into the thermoplastic film. Because the amorphous thermoplastic film 36 can be prefabricated to a controlled thickness, the cast thermoplastic joint 31 can have an edge line thickness that is both consistent and controllable. Thermoplastic gasket 31 can also exhibit improved toughness compared to gaskets that are based on bonding adhesives. Additionally, the amorphous thermoplastic film 36 can be selected to have a desired hardness that may be less than that of the thermoset composite components 152, 154, allowing the thermoplastic fused joint 31 to better absorb energy because of shock, vibration or impacts observed by the structure. composite. Thus, the thermoset composite structure 150 can exhibit better impact strength.
    [0063] Modalities of the description may find use in a variety of potential applications, particularly in the transportation industry, including, for example, aerospace, marine, automotive and other applications where composite components are joined together. In the aircraft industry, the described joining method can be used to produce high-performance, low-cost integrated structures such as longitudinal beams of various cross-sectional shapes, torque boxes used for doors, flight control structures, wing and airframe structures. fuselage. Thus, referring now to Figures 23 and 24, embodiments of the description can be used in the context of a method of manufacturing and servicing an aircraft 164 shown in Figure 23 and an aircraft 166 shown in Figure 24. During pre-production, the method exemplar 164 may include specification and design 168 of aircraft 166 and purchase of material 170. During production, component and subassembly 172 manufacture and system integration 174 of aircraft 166 takes place. in order to be put into service 178. While in service by a customer, aircraft 166 is scheduled for routine maintenance and service 180, which may also include modification, reconfiguration, overhaul, and so on.
    [0064] Each of the processes of method 164 can be performed or done by a system integrator, a third party and/or an operator (e.g., a customer). For purposes of this description, a system integrator may include, without limitation, any number of aircraft manufacturers and main system subcontractors; a third party may include, without limitation, any number of vendors, subcontractors and suppliers; and an operator can be an airline, leasing company, military entity, service organization, and so on.
    [0065] As shown in Figure 24, aircraft 166 produced by exemplary method 164 may include a mainframe 182 with a plurality of systems 184 and an interior 186. Examples of high-level systems 184 include one or more than one propulsion system 188, an electrical system 190, a hydraulic system 192, and an environmental system 194. Any number of other systems may be included. Although one is shown as an aerospace example, the principles in the description can be applied to other industries, such as marine and automotive industries.
    [0066] Systems and methods conceived herein may be employed during any one or more of the stages of the production and service method 164. For example, components or subassemblies corresponding to the production process 172 may be manufactured or made in a manner similar to the components or subassemblies produced while the 166 aircraft is in service. Also, one or more apparatus modalities, method modalities, or a combination thereof may be utilized during production stages 172 and 174, for example, substantially shipping the assembly or reducing the cost of an aircraft 166. Similarly, one or more apparatus modes, method modes, or a combination of these may be used while the aircraft 166 is in service, for example, and without limitation, for maintenance and service 180.
    [0067] The description of the different illustrative modalities has been presented for purposes of illustration and description, and should not be exhaustive or limited to the modalities as described. Many modifications and variations will be apparent to those skilled in the art. Additionally, different illustrative embodiments may provide different advantages compared to other illustrative embodiments. The selected modality or modalities are chosen and described in order to better explain the principles of the modalities, the practical application, and to allow others skilled in the art to understand the description for various modalities with various modifications suitable for the particular use contemplated.
    权利要求:
    Claims (6)
    [0001]
    1. Method for joining two thermoplastic components, characterized in that it comprises the steps of: producing (38) a first thermoplastic composite component (32) by placing a first amorphous thermoplastic film (36a) on a first thermoplastic pre-preg stack (32a ), and co-consolidating the first amorphous thermoplastic film and the first thermoplastic pre-preg stack to provide a layer of the first amorphous thermoplastic film onto the first thermoplastic pre-peg stack; producing (40) a second thermoplastic composite component by placing a second amorphous thermoplastic film (36b) on a second thermoplastic pre-preg stack (32a), and co-consolidating the second amorphous thermoplastic film and the second thermoplastic pre-preg stack to provide a layer of second amorphous thermoplastic film on second stack of thermoplastic pre-peg; assembling (42) the first and second thermoplastic composite components, including placing the first and second amorphous thermoplastic films against each other; pressing (44) the first and second amorphous thermoplastic films together by applying pressure to the first and second thermoplastic composite components; and melting (46) the first and second amorphous thermoplastic films together at a temperature below 246°C (475°F); wherein each of the first and second thermoplastic pre-preg is PEEK; and wherein each of the first and second amorphous thermoplastic films is PES.
    [0002]
    2. Method according to claim 1, characterized in that producing the first thermoplastic composite component includes the steps of: placing the first amorphous thermoplastic film against a joining surface (37) of the first thermoplastic pre-preg stack, and co-consolidating the first amorphous thermoplastic film and the first thermoplastic pre-preg stack include heating the first thermoplastic pre-preg stack to the melting temperature of the pre-preg in the first stack thereof and compressing the first thermoplastic pre-preg stack with the first film amorphous thermoplastic.
    [0003]
    3. Method according to any one of claims 1 or 2, characterized in that co-consolidating the second amorphous thermoplastic film and the second thermoplastic pre-preg stack includes the steps of: heating the second amorphous thermoplastic film to its transition temperature glass, heat the second thermoplastic pre-preg to its melting temperature, and compress the second thermoplastic pre-preg stack with the second amorphous thermoplastic film.
    [0004]
    4. The method of claim 2, characterized in that heating the first thermoplastic pre-preg stack to its melting temperature includes heating the first thermoplastic pre-preg stack to a temperature greater than 343 °C (650 °C F).
    [0005]
    5. Method according to any one of claims 1 to 4, characterized in that each of the first and second amorphous thermoplastic films has a thickness between 5 mm and 7 mm.
    [0006]
    6. Integrated thermoplastic structure, characterized in that it has thermoplastic components joined by the method as defined in any of the preceding claims.
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    同族专利:
    公开号 | 公开日
    BR112015012036A8|2019-10-01|
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    WO2014088704A2|2014-06-12|
    KR102248479B1|2021-05-06|
    EP2931497A2|2015-10-21|
    EP2931497B1|2021-03-24|
    KR20150091309A|2015-08-10|
    CA2888974C|2020-12-15|
    JP6411359B2|2018-10-24|
    CN104822511A|2015-08-05|
    BR112015012036A2|2017-07-11|
    WO2014088704A3|2015-01-15|
    JP2015536265A|2015-12-21|
    US20150298388A1|2015-10-22|
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    法律状态:
    2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
    2019-12-10| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2021-03-30| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2021-07-27| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-09-08| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/10/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US13/693,958|2012-12-04|
    US13/693,958|US20150298388A1|2012-12-04|2012-12-04|Joining Composite Components Using Low Temperature Thermoplastic Film Fusion|
    PCT/US2013/065238|WO2014088704A2|2012-12-04|2013-10-16|Joining composite components using low temperature thermoplastic film fusion|
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